学习及工作经历

2008年9月-2012年7月，中国石油大学（华东），应用化学专业，学士；

2012年8月-2017年1月，中科院大连化学物理研究所，工业催化专业，博士；

2017年1月-2018年1月，中科院大连化学物理研究所，洁净能源国家实验室（筹），助理研究员

2018年1月-至今，中科院大连化学物理研究所，洁净能源国家实验室（筹），副研究员

 

研究兴趣（个人的研究方向）

1、N,P配体聚合物单原子催化剂上氢甲酰化（氢甲胺化、氢羧基化等）反应的基础研究及工业化

    与项目攻关小组一起将固定床乙烯氢甲酰化技术推向产业应用，实现了全球首套单原子催化装置(5万吨/年)的落地投产。在项目中主要负责具有原创性的关键性技术“单原子催化剂的制备”，工厂一线出差两年，克服系列“卡脖子”技术难点，最终实现单原子催化剂的吨级量产。正在进行固定床丙烯氢甲酰化制丁辛醇原创技术的开发，将实验室研发的原创成果推向工业应用(目前已经完成了立升级的单管中试)。

 

2、在“碳达峰、碳中和”政策背景下，研究以CO₂作为替代羰源的高效催化转化催化剂

 

希望合作的方向、领域

1. 氢甲酰化反应机理的计算与模拟

2. 高效N,P配体合成方法的开发

 

代表性文章/专利

1. Cunyao Li, Li Yan*, Lanlu Lu, Kai Xiong, Wenlong Wang, Miao Jiang, Jia Liu, Xiangen Song, Zhuangping Zhan, Zheng Jiang and Yunjie Ding*. Single atom dispersed Rh-Biphephos&PPh₃@porous organic copolymers：Highly efficient catalysts for continuous fixed-bed hydroformylation of propene. Green Chem., 2016, 18: 2995-3005 (highlighted in back cover) .

2. Cunyao Li#, Wenlong Wang#, Li Yan*, Yuqing Wang, Miao Jiang and Yunjie Ding*. Phosphonium Salt & ZnX2-PPh3 Integrated Hierarchical POPs: Tailorable Synthesis and Highly Efficient Cooperative Catalysis in CO₂ Utilization. J. Mater. Chem. A., 2016, 4: 16017-16027(contributed equally).

3. Cunyao Li, Keju Sun, Wenlong Wang, Li Yan*, Xueping Sun, Yuqing Wang, Kai Xiong, Zhuangping Zhan, Zheng Jiang, Yunjie Ding*. Xantphos doped Rh/POPs-PPh3 catalyst for highly selective long-chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of Xantphos and PPh₃. J. Catal., 2017, 353: 123-132.

4. Cunyao Li, Kai Xiong, Li Yan*, Miao Jiang, Xiangen Song, Tao Wang, Xingkun Chen, Zhuangping Zhan and Yunjie Ding*. Designing highly efficient Rh/CPOL-bp&PPh₃ heterogenous catalysts for hydroformylation of internal and terminal olefins. Catal. Sci. Technol., 2016, 6: 2143-2149.

5. Cunyao Li, Wenlong Wang, Li Yan* and Yunjie Ding*. A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts. Front. Chem. Sci. Eng., 2018, 12: 113-123.

6. Cunyao Li, Li Yan, Wenlong Wang, Yuqing Wang, Miao Jiang and Yunjie Ding*. Design and Synthesis of N,P-ligands based POPs (Porous Organic Polymers) and Their Applications in Heterougeneous Catalysis. POLYMER BULLETIN, 2018, 6: 32-50.

7. Wenlong Wang#, Cunyao Li#, Li Yan*, Yuqing Wang, Miao Jiang and Yunjie Ding*. Ionic Liquid/Zn-PPh3 Integrated Porous Organic Polymers Featuring Multifunctional Sites: Highly Active Heterogeneous Catalyst for Cooperative Conversion of CO₂ to Cyclic Carbonates. ACS Catal., 2016, 6, 6091-6100 (contributed equally).

8. Wen-Hao Li#, Cun-Yao Li#, Yan Li, Hai-Tao Tang, Heng-Shan Wang, Ying-Ming Pan and Yun-Jie Ding*. Palladium-metalated porous organic polymers as recyclable catalysts for chemoselective decarbonylation of aldehydes. Chem. Commun., 2018, 54: 8446-8449. (contributed equally, highlighted in front cover)

9. Wen-Hao Li, Cun-Yao Li, Huan-Yan Xiong, Yang Liu, Wen-Yong Huang, Guang-Jun Ji, Zheng Jiang, Hai-Tao Tang*, Ying-Ming Pan* and Yun-Jie Ding*. Constructing Mononuclear Palladium Catalysts by Precoordination/Solvothermal Polymerization: Recyclable Catalyst for Regioselective Oxidative Heck Reactions. Angew. Chem. Int. Ed., 2019, 58(8): 2448-2453.

10. Gunjun Ji#, Cunyao Li#; Dong Xiao, Guoqing Wang, Zhao Sun, Miao Jiang, Li Yan*, Guangjin Hou*, Yunjie Ding*, The effect of the position of cross-linkers on the structure and microenvironment of PPh3 moiety in porous organic polymers. J. Mater. Chem. A., 2021, 9(14): 9165-9174(contributed equally).

11. Wenlong Wang#, Cunyao Li#, Heng Zhang, Jiangwei Zhang, Lanlu Lu, Zheng Jiang, Lifeng Cui, Hongguang Liu*, Li Yan*, Yunjie Ding*, Enhancing the activity, selectivity, and recyclability of Rh/PPh3 system-catalyzed hydroformylation reactions through the development of a PPh3-derived quasi-porous organic cage as a ligand, Chinese Journal of Catalysis, 2021, 42(7): 1216-1226(contributed equally).

12. Guangjun Ji#, Cunyao Li#, Guoqing Wang, Lei Ma, Miao Jiang, Li Yan*, Yunjie Ding*, Precisely design PPh3-based polymer by hybrid coupling of monomers for high efficient hydroformylation, Microporous and Mesoporous Materials, 2021, 111508. (contributed equally).

13. Yun-Bing Zhou#, Cun-Yao Li#, Min Lin, Yun-Jie Ding and Zhuang-Ping Zhan. A Polymer-Bound Monodentate-P-Ligated Palladium Complex as a Recyclable Catalyst for the Suzuki–Miyaura Coupling Reaction of Aryl Chlorides. Adv. Synth. Catal., 2015, 357: 2503-2508 (contributed equally).

 

所获奖励及荣誉（研究所/学会/市/省/国家级等）

大连市青年科技之星（2021年）

首届中国石化联合会CPCIF-Clariant可持续发展青年创新奖（2018年）

首届中科院大连化物所优秀青年博士人才（2018年）

中国科学院大学优秀毕业生，北京普通高校优秀毕业生（2017年）

博士研究生国家奖学金，延长石油优秀博士生奖学金，中国科学院大学三好学生（2016年）

联系方式

电话：0411-84379057（能源楼1号楼603）

邮箱：licunyao2008@dicp.ac.cn

个人主页：http://people.ucas.edu.cn/~licunyao